NickelMaghrebV1, Main, Exploration, bibRecord, 001018

Crystal structure and magnetic properties of Ba2Ni(PO4)2

Identifieur interne : 001018 ( Main/Exploration ); précédent : 001017; suivant : 001019

Crystal structure and magnetic properties of Ba2Ni(PO4)2

Auteurs : B. Elbali [Maroc] ; A. Boukhari [Maroc] ; J. Aride ; M. Belaiche ; F. Abraham [France] ; M. Drillon [France]

Source :

European journal of solid state and inorganic chemistry [ 0992-4361 ] ; 1994.

RBID : Pascal:94-0337245

Descripteurs français

Pascal (Inist)
- Etude expérimentale, XRD, Structure cristalline, Composé quaternaire, Nickel phosphate, Baryum phosphate, Susceptibilité magnétique, Chaleur massique magnétique, Antiferromagnétisme, Interaction échange, Propriété thermodynamique, Structure tunnel, 6166F, 6110M, 7540C, Ba2Ni(PO4)2, Ba Ni O P.

English descriptors

KwdEn :
- Antiferromagnetism, Barium phosphates, Channel structure, Crystal structure, Exchange interactions, Experimental study, Magnetic specific heat, Magnetic susceptibility, Nickel phosphates, Quaternary compounds, Thermodynamic properties, XRD.

Abstract

The structure of the title compound was solved by single crystal X-ray diffraction. It crystallizes in the monoclinic system with the space group P2₁/n. The cell parameters are a=5.312, b=8.789, c=16.067Å, β=90.72°, Z=4. The structure has been refined from 2979 independent reflections to R=0.031 (R_w=0.039). The three-dimensional framework could be described from corner and edge-sharing NiO₆ octahedra and PO₄ tetrahedra creating two types of tunnels where are located the barium ions. Magnetic thermal susceptibility has been described in terms of antiferromagnetic isotropic interactions in dimers of Ni²⁺ (S=1)

Affiliations:

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Le document en format XML

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Ni(PO<sub>4</sub>
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<term>Barium phosphates</term>
<term>Channel structure</term>
<term>Crystal structure</term>
<term>Exchange interactions</term>
<term>Experimental study</term>
<term>Magnetic specific heat</term>
<term>Magnetic susceptibility</term>
<term>Nickel phosphates</term>
<term>Quaternary compounds</term>
<term>Thermodynamic properties</term>
<term>XRD</term>
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<keywords scheme="Pascal" xml:lang="fr"><term>Etude expérimentale</term>
<term>XRD</term>
<term>Structure cristalline</term>
<term>Composé quaternaire</term>
<term>Nickel phosphate</term>
<term>Baryum phosphate</term>
<term>Susceptibilité magnétique</term>
<term>Chaleur massique magnétique</term>
<term>Antiferromagnétisme</term>
<term>Interaction échange</term>
<term>Propriété thermodynamique</term>
<term>Structure tunnel</term>
<term>6166F</term>
<term>6110M</term>
<term>7540C</term>
<term>Ba2Ni(PO4)2</term>
<term>Ba Ni O P</term>
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<front><div type="abstract" xml:lang="en">The structure of the title compound was solved by single crystal X-ray diffraction. It crystallizes in the monoclinic system with the space group P2<sub>1</sub>
/n. The cell parameters are a=5.312, b=8.789, c=16.067Å, β=90.72°, Z=4. The structure has been refined from 2979 independent reflections to R=0.031 (R<sub>w</sub>
=0.039). The three-dimensional framework could be described from corner and edge-sharing NiO<sub>6</sub>
 octahedra and PO<sub>4</sub>
 tetrahedra creating two types of tunnels where are located the barium ions. Magnetic thermal susceptibility has been described in terms of antiferromagnetic isotropic interactions in dimers of Ni<sup>2+</sup>
 (S=1)</div>
</front>
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Crystal structure and magnetic properties of Ba2Ni(PO4)2

Crystal structure and magnetic properties of Ba2Ni(PO4)2

Source :

Descripteurs français

English descriptors

Abstract

Links toward previous steps (curation, corpus...)

Le document en format XML

Pour manipuler ce document sous Unix (Dilib)

Pour mettre un lien sur cette page dans le réseau Wicri